Hastelloy B - 3

Hastelloy B - 3

Hastelloy B-3 is a solution-strengthened nickel-molybdenum (Ni-Mo) alloy, an improved version of Hastelloy B-2 with further optimized thermal stability. It exhibits exceptional resistance to corrosion by reducing acids, particularly excelling in full-concentration hydrochloric acid below boiling point. By optimizing its chemical composition (with small additions of chromium, aluminum, and titanium), B-3 significantly reduces the tendency for harmful phases (such as Ni₄Mo) to precipitate during hot working and welding. This enhances thermal stability and sensitization resistance while maintaining excellent intergranular corrosion resistance. The alloy is widely used in harsh environments such as chemical processing, high-pressure reactors, distillation columns, acetic acid production, and pesticide synthesis.
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Description
Technical Parameters

Products Features

High-Temperature Oxidation Resistance

Exceptional Resistance to Reducing Acid Corrosion

High molybdenum content (27–32%) endows Hastelloy B-3 with near-perfect corrosion resistance in reducing media such as hydrochloric acid, dilute sulfuric acid, and phosphoric acid, far surpassing conventional austenitic stainless steels and most nickel-based alloys.

High-Temperature Corrosion Resistance

Excellent Hydrochloric Acid Corrosion Resistance

It remains stable in full-concentration hydrochloric acid below boiling point, with no tendency for pitting or intergranular corrosion. It also withstands non-oxidizing acids such as hydrogen chloride gas, formic acid, and acetic acid.

High Stability

Enhanced Thermal Stability

Compared to B-2, B-3 significantly reduces the precipitation rate of harmful intermetallic phases (such as Ni₄Mo) during hot working and welding through precise control of elements like iron, chromium, aluminum, and titanium. This results in better intergranular corrosion resistance in the as-welded condition and reduced sensitivity to thermal history.

Good Processability

Good Intergranular Corrosion Resistance

Ultra-low carbon content (≤0.01%) and optimized alloy design significantly reduce the risk of carbide and harmful phase precipitation in the weld heat-affected zone. It can be used in most corrosive environments in the as-welded condition without requiring post-weld heat treatment.

High-Temperature Oxidation Resistance

Moderate Resistance to Sulfuric and Phosphoric Acids

It performs well in sulfuric and phosphoric acids at moderate concentrations or lower, especially in non-oxidizing acid solutions containing chlorides or fluorides.

High-Temperature Corrosion Resistance

Good Formability and Weldability

It can be formed by conventional hot and cold working processes and has good weldability (GTAW, GMAW, SMAW). It is recommended to use matching Hastelloy B-3 filler wire. Oxidizing atmospheres (such as nitric acid or oxygen-containing solutions) should be avoided, as they significantly increase corrosion rates.

Technical Specifications

Chemical Composition

 

Element

Standard Requirements

Notes

Ni

Remaining quantity(≥65%)

Matrix elements that provide corrosion resistance

Mo

27.0 – 32.0%

Core components that provide acid resistance

Fe

1.5 – 3.0%

Improve hot workability, but strict control is required

Cr

1.0 – 3.0%

Add a small amount to enhance adaptability in moderately oxidative environments

Co

≤ 3.0%

Impurities or permissible additives

C

≤ 0.01%

Ultra-low carbon content, preventing intergranular corrosion

Si

≤ 0.10%

w silicon content to prevent intergranular corrosion tendency

Al

≤ 0.50%

Deoxidizing and stabilizing elements

Ti

≤ 0.20%

Stabilizing elements to reduce the precipitation of harmful phases

Mn

≤ 3.0%

A small amount of oxygen absorber

P

≤ 0.030%

Impurity elements

S

≤ 0.010%

Prevent hot brittleness

Physical Properties

 

Property

Value/Range

Test Conditions

Density

9.22 g/cm³

Room temperature (20°C)

Melting Point

1370 – 1418°C

-

Coefficient of Thermal Expansion (20-100°C)

13.6 × 10⁻⁶ /K

-

Mechanical Properties (Annealed Condition, Typical Values)

 

Property

Typical Value

Specification

Tensile Strength

≥ 760 MPa

ASTM B333 / B622

Strength (0.2% Offset)

≥ 350 MPa

ASTM B333 / B622

Elongation

≥ 40%

ASTM B333 / B622

Hardness

≤ 100 HRB

-

High-temperature performance

 
 

Antioxidant Performance:

Hastelloy B-3 is primarily designed for moderately low-temperature reducing corrosive environments (long-term use at ≤ 450°C). Its corrosion resistance drops sharply in oxidizing atmospheres (such as oxygen-containing solutions or nitric acid) and is not recommended for oxidizing media. However, compared to B-2, B-3 has slightly improved tolerance to trace oxidizing impurities due to its small chromium content.

Pitting Resistance Equivalent (PREN): PREN = %Cr + 3.3×%Mo + 16×%N. With a lower chromium content (1–3%), the PREN value typically ranges between 10–20, making it unsuitable for oxidizing environments containing chlorides. This alloy is not designed for pitting resistance but focuses on uniform corrosion resistance in reducing acids.

Critical Pitting Temperature (CPT): Not applicable (not resistant to corrosion in chloride-containing oxidizing environments).

Suitable Media:

Hydrochloric acid (all concentrations, below boiling point)

Dilute sulfuric acid (≤60% concentration)

Phosphoric acid (non-oxidizing conditions)

Organic acids such as formic acid, acetic acid, and propionic acid

Hydrogen chloride gas (dry or reducing conditions)

Chemical media for acetic acid synthesis, pesticide synthesis, etc.

Note: Prohibited for use in strongly oxidizing media such as nitric acid, hydrochloric acid containing iron/copper ions, and oxygen-containing solutions.

Steel Plate Processing
Steel Coil Processing
Steel Pipe Processing
Steel Bar Processing
 

Hastelloy B-3 is specifically designed for corrosive environments involving moderately low-temperature reducing acids. It is recommended for use in the following areas:

 

Application Fields

  •  

    Hydrochloric Acid Handling Equipment: Storage tanks, heat exchangers, towers, pumps, valves, and piping.

  •  

    Acetic Acid/Synthesis: Reactors, distillation columns, reboilers.

  •  

    Pesticide Production: Synthesis equipment for chlorinated/fluorinated pesticide intermediates.

  •  

    Phosphoric Acid Concentration: Non-oxidizing phosphoric acid evaporators and heaters.

  •  

    Formic Acid/Propionic Acid Plants: Corrosion-resistant components for organic acids.

  •  

    Chlor-Alkali Industry: Hydrogen chloride gas coolers, drying towers.

  •  

    Fine Chemicals: Reactors and agitators operating in reducing acid environments.

  •  

    Pharmaceutical Industry: Synthesis of certain acidic drug intermediates.

  •  

    Flue Gas Desulfurization (FGD): Limited to absorber zones under non-oxidizing conditions only.

  •  

    Metal Acid Pickling: Hydrochloric acid pickling tanks and associated equipment.

Delivery and Customization

We offer flexible and reliable supply chain solutions to ensure you receive Hastelloy B-3 materials that perfectly match your project requirements.

Form

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Sheet/Plate
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Bar/Rod
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Seamless Pipe
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Strip/Sheet Coil
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Wire/Wire Rod

Conventional Range

Thickness: 0.5 - 100 mm
Width: ≤ 1500 mm
Length: Customizable

Diameter Φ6-500mm

Outer diameter Φ10-300mm

Thickness: 0.1 – 3.0 mm
Width: 10 – 600 mm

Diameter Φ0.5-10mm

Customization Capability

Special thick/thin rolling, ultra-wide plates; special surface treatment, fixed-length cutting

Large-sized forged bars (up to Φ800 mm), special-shaped bars, and various heat treatment conditions

Large-diameter thick-walled pipes, special alloy composition; Pipe end processing (beveling, fixed length)

Different hardness conditions, special heat treatments (stabilization treatment, grain size control), acid-washed surfaces, electrolytic polishing, coatings, or special protective films

Special surface treatment, precision drawing

Why Choose Us? - Reliable engineering technology. Dependable delivery.

We are not just a supplier, but a trusted materials partner for you in China.

Sample Support & Quick Response

Vertically Integrated Production

Own 20,000㎡ facility with 10+ automated lines (8,000+ tons/year). In-house tooling & die center enables rapid customization and effective cost control - no middleman markup.

Full Traceability

Strict Quality Control at Every Stage

Full traceability across key QC checkpoints throughout production. 100% compliant with ASTM/ASME, EN, and GB standards. Material test reports available with every shipment.

Professional Logistics & Packaging

Reliable Delivery & Export Packaging

10+ years exporting to Europe, North America, Southeast Asia & Middle East with waterproof and anti-rust protection, combined with flexible shipping options ensures safe and on-time arrival.

Complete Export Documentation

Sample Validation Before Mass Production

We provide free samples for quality verification, allowing you to place bulk orders only after approval. We ensure consistency from sample to mass production by accurate dimensional measurement and transparent manufacturing.

FAQ

Q: What are the main advantages of Hastelloy B-3?

 

Q: What heat treatment is required for Hastelloy B-3?

 

Q: What is the maximum service temperature?

 

Q: What is the difference between it and Hastelloy B-2?

 

 

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