Hastelloy C-22

Hastelloy C-22

Hastelloy C-22 (UNS N06022) is an ultra-low carbon nickel-chromium-molybdenum-tungsten alloy, renowned as the 'universal performer' among nickel-based corrosion-resistant alloys. Through a unique chemical composition design (high chromium 20.0-22.5%, high molybdenum 12.5-14.5%, and appropriate tungsten 2.5-3.5%), this alloy exhibits excellent corrosion resistance in both oxidizing and reducing conditions, offering the best overall corrosion resistance among similar Ni-Cr-Mo alloys. C-22 demonstrates exceptional resistance to pitting, crevice corrosion, and chloride stress corrosion cracking, and is one of the few materials capable of withstanding corrosion from moist chlorine gas, hypochlorites, and chlorine dioxide solutions. Additionally, its ultra-low carbon content and low impurity levels ensure minimal degradation of corrosion resistance in the heat-affected zone after welding, eliminating the need for post-weld heat treatment. It is widely used in extreme corrosive environments such as chemical processing, flue gas desulfurization, acetic acid/pesticide production, pharmaceuticals, oil and gas extraction, and nuclear waste handling.
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Description
Technical Parameters

Products Features

High-Temperature Oxidation Resistance

Excellent Oxidation and Reduction Resistance

The high chromium content (20.0-22.5%) ensures the formation of a dense and stable Cr₂O₃ passivation film in oxidizing media (e.g., nitric acid, sulfuric acid containing Fe³⁺/Cu²⁺, moist chlorine gas). The high molybdenum content (12.5-14.5%) and tungsten addition (2.5-3.5%) provide superior uniform corrosion resistance in reducing media (e.g., hydrochloric acid, dilute sulfuric acid). Compared to similar nickel-based alloys such as C-276, C-4, and 625, C-22 offers better and more comprehensive corrosion resistance, enabling it to handle complex service conditions ranging from strongly oxidizing to strongly reducing environments. It is an ideal single material choice for multiple corrosive media.

High-Temperature Corrosion Resistance

Exceptional Resistance to Pitting, Crevice Corrosion, and Stress Corrosion Cracking

The synergistic effect of high chromium, molybdenum, and tungsten content results in a pitting resistance equivalent (PREN = %Cr + 3.3×%Mo + 16×%N) of over 65 for C-22, providing outstanding resistance to pitting and crevice corrosion in chloride-containing environments. According to ASTM G48 standards (6% FeCl₃ solution test), the critical pitting temperature (CPT) of C-22 exceeds 150°C, and the critical crevice corrosion temperature (CCT) is approximately 80°C, significantly outperforming 316L stainless steel and most other similar alloys. Additionally, C-22 exhibits immunity to chloride-induced stress corrosion cracking, complying with NACE MR0175/ISO 15156-3 standards, making it suitable for harsh conditions such as acidic gas fields.

High Stability

Superior Weldability and Thermal Stability

Ultra-low carbon (≤0.015%) and extremely low silicon content strictly limit impurities such as iron and cobalt, preventing the formation of harmful intermetallic phases (e.g., σ phase) during hot working and welding. Even in the heat-affected zone after welding, its corrosion resistance remains almost unaffected. Post-weld solution annealing is not required, allowing direct use in corrosive service conditions, greatly simplifying equipment manufacturing processes.

Good Processability

Good Formability and Weldability

It can be formed by conventional hot and cold working processes. Excellent cold formability, due to good ductility, allows easy cold rolling and cold drawing. The recommended hot working temperature range is 950-1200°C. It has good weldability (GTAW/TIG, GMAW/MIG, SMAW, etc.) and is recommended to use ERNiCrMo-10 filler wire (AWS A5.14 standard). Interpass temperature should be controlled at ≤100°C. Post-weld solution annealing is not required, and it can be directly used in corrosive service conditions.

Technical Specifications

Chemical Composition

 

Element

Standard Requirements

Notes

Ni

Remaining quantity(≥56.0%)

Matrix elements that ensure the stability of face-centered cubic austenitic structure and provide excellent resistance to stress corrosion cracking

Cr

20.0 - 22.5%

Provides antioxidant and corrosion-resistant properties, which are key elements in forming a dense passivation film

Fe

2.0 - 6.0%

Strictly control the scope while balancing intensity and cost

Mo

12.5 - 14.5%

Significantly improve resistance to corrosion by reducing acids, pitting corrosion, and crevice corrosion

W

2.5 - 3.5%

Enhance pitting corrosion resistance and stabilize the passivation film in synergy with molybdenum

Co

≤ 2.5%

Strictly control to reduce the impact of impurities

C

≤ 0.015%

Ultra-low carbon content, preventing intergranular corrosion and eliminating the risk of carbide precipitation

Mn

≤ 2.0%

Deoxidizer, improve hot working properties

Si

≤ 0.08%

Extremely low silicon content, preventing intergranular corrosion tendency

V

≤ 0.35%

Minor alloying elements

P

≤ 0.025%

Impurity elements, strictly controlled

S

≤ 0.020%

Prevent hot brittleness

Physical Properties

 

Property

Value/Range

Test Conditions

Density

8.69 g/cm³

Room temperature (20°C)

Melting Point

1357 - 1399°C

-

Coefficient of Thermal Expansion (20-100°C)

12.4 × 10⁻⁶ /K

-

Elastic modulus (Young's modulus)

205.5 GPa

-

Thermal conductivity (20°C)

11.1 W/(m·K)

Room Temperature

Specific Heat Capacity

0.385 × 10³ J/(kg·K)

-

Mechanical Properties (Annealed Condition, Typical Values)

 

Property

Typical Value

Specification

Tensile Strength

≥ 690 MPa

ASTM B574

Yield Strength (0.2% Offset)

≥ 283 MPa

ASTM B574

Elongation

≥ 40%

ASTM B574

Hardness

≤ 100 HRB (or ≤ 220 HB)

-

High-temperature performance

 
 

Antioxidant Performance:

This alloy maintains structural and mechanical stability when used long-term below 600°C and can withstand higher temperature oxidizing atmospheres in the short term. C-22 also resists various corrosive environments at elevated temperatures up to 677°C. However, for long-term use, it is recommended not to exceed 400°C to avoid performance degradation caused by the precipitation of harmful phases such as sigma phase.

Thermal Stability: C-22 exhibits excellent resistance to intergranular precipitate formation in the medium-to-high temperature range of 650-1040°C. Compared with the earlier C-276 alloy, C-22 has an extremely low tendency for harmful phase precipitation during prolonged exposure in this temperature range. It possesses good intergranular corrosion resistance in the weld heat-affected zone and can be used directly in the as-welded condition.

Pitting Resistance Equivalent Number (PREN): The PREN value is calculated as PREN = %Cr + 3.3×%Mo + 16×%N. C-22 has a PREN value ≥ 65 (with some data reaching 68), which is significantly higher than that of 316L (~25) and 904L (~35). This provides exceptional resistance to pitting and crevice corrosion in chloride-containing environments.

Critical Pitting Temperature (CPT): In 6% FeCl₃ solution (per ASTM G48 standard), the CPT of C-22 exceeds 150°C. By comparison, stainless steel 316L is approximately 15°C, super duplex steel 2507 is about 60°C, and C-276 alloy is lower than C-22.

Critical Crevice Corrosion Temperature (CCT): The CCT is approximately 80°C (with some data indicating 75-85°C), placing it among the leading alloys in its class. It is particularly suitable for structures prone to crevice corrosion such as heat exchanger tube plates and flange gasket faces.

Applicable Media:

1. Chloride-containing seawater, saltwater, and brines

2. Sulfuric acid, phosphoric acid, nitric acid, formic acid, acetic acid, and other organic acids

3. Wet flue gas desulfurization (FGD) slurries

4. Oxidizing-reducing mixed acids (e.g., sulfuric acid + hydrochloric acid mixtures)

5. Paper pulp bleaching solutions (containing chlorine and chlorine dioxide)

6. Wet chlorine gas, hypochlorites, and chlorine dioxide solutions (C-22 is one of the few materials resistant to such corrosive conditions)

7. Acidic gas environments containing H₂S/CO₂

8. High-temperature and high-pressure water (nuclear power secondary circuit)

Note: This alloy is approved by NACE Standard MR0175/ISO 15156-3 for use in sour gas environments. Its operating temperature range spans from -200°C to 400°C and is suitable for pressure vessels.

Steel Plate Processing
Steel Coil Processing
Steel Pipe Processing
Steel Bar Processing
 

Hastelloy C-22 is specifically designed for harsh corrosive environments at moderate to low temperatures and is recommended for use in the following areas:

 

Application Fields

  •  

    Chemical and Petrochemical Industries: Reactors, distillation columns, heat exchangers, piping, and valves handling sulfuric acid, hydrochloric acid, phosphoric acid, nitric acid, and halide-containing media. It is particularly suitable for acetic acid/acetic anhydride production, components of chlorinated organic compounds, and catalytic systems. This material is especially well-suited for high-temperature environments with impure inorganic and organic acids (such as formic and acetic acids) and seawater corrosion.

  •  

    Flue Gas Desulfurization (FGD): Absorber spray layers, reheaters, flue gas cleaning systems, dampers, and agitators, providing resistance to severe corrosion from high concentrations of chloride ions and sulfurous/sulfuric acids in desulfurization slurry.

  •  

    Acetic Acid and Pesticide Production: Reactors for acetic acid/acetic anhydride, distillation columns, and equipment for synthesizing chlorinated/fluorinated pesticide intermediates.

  •  

    Pharmaceuticals and Fine Chemicals: Suitable for multi-functional production equipment requiring high purity and resistance to a variety of chemicals. Synthesis reactors and active pharmaceutical ingredient production lines ensure product purity and equipment reliability.

  •  

    Paper Industry: Digesters and bleaching equipment resistant to corrosion from chlorine and chlorine dioxide-based bleaching solutions.

  •  

    Oil and Gas: Pipelines, platform equipment, and downhole tools for sour gas fields containing H₂S, CO₂, and Cl⁻. Complies with NACE MR0175 (ISO 15156-3) standards.

  •  

    Environmental Engineering: Waste incineration flue gas purification equipment, incineration scrubbers, wastewater treatment evaporators, and waste acid/waste liquid evaporators.

  •  

    Marine Engineering and Seawater Desalination: Seawater cooling pipes, heat exchangers, pumps, valves, and desalination plants, resisting high salinity and microbial corrosion.

  •  

    Salt and Salt Chemical Industries: Evaporators, crystallizers, and salt slurry pumps, suitable for process environments with high chloride concentrations.

  •  

    Special Industrial Applications: Rollers for glass paper manufacturing, rollers for chlorination systems, zinc electroplating tanks, geothermal wells, hydrofluoric acid furnace cleaners, nuclear fuel reprocessing, plate heat exchangers, sulfonation systems, and overlay-welded valves.

Delivery and Customization

We offer flexible and reliable supply chain solutions to ensure you receive Hastelloy C-22 materials that perfectly match your project requirements.

Form

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Sheet/Plate
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Bar/Rod
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Seamless Pipe
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Strip/Sheet Coil
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Wire/Wire Rod

Conventional Range

Thickness: 0.5 - 100 mm
Width: ≤ 1500 mm
Length: Customizable

Diameter Φ6-500mm

Outer diameter Φ10-300mm

Thickness: 0.1 – 3.0 mm
Width: 10 – 600 mm

Diameter Φ0.5-10mm

Customization Capability

Special thick/thin rolling, ultra-wide plates; special surface treatment, fixed-length cutting

Large-sized forged bars (up to Φ800 mm), special-shaped bars, and various heat treatment conditions

Large-diameter thick-walled pipes, special alloy composition; Pipe end processing (beveling, fixed length)

Different hardness conditions, special heat treatments (stabilization treatment, grain size control), acid-washed surfaces, electrolytic polishing, coatings, or special protective films

Special surface treatment, precision drawing

Why Choose Us? - Reliable engineering technology. Dependable delivery.

We are not just a supplier, but a trusted materials partner for you in China.

Sample Support & Quick Response

Vertically Integrated Production

Own 20,000㎡ facility with 10+ automated lines (8,000+ tons/year). In-house tooling & die center enables rapid customization and effective cost control - no middleman markup.

Full Traceability

Strict Quality Control at Every Stage

Full traceability across key QC checkpoints throughout production. 100% compliant with ASTM/ASME, EN, and GB standards. Material test reports available with every shipment.

Professional Logistics & Packaging

Reliable Delivery & Export Packaging

10+ years exporting to Europe, North America, Southeast Asia & Middle East with waterproof and anti-rust protection, combined with flexible shipping options ensures safe and on-time arrival.

Complete Export Documentation

Sample Validation Before Mass Production

We provide free samples for quality verification, allowing you to place bulk orders only after approval. We ensure consistency from sample to mass production by accurate dimensional measurement and transparent manufacturing.

FAQ

Q: What are the main advantages of Hastelloy C-22?

 

Q: What heat treatment is required for Hastelloy C-22?

 

Q: What is the maximum service temperature?

 

Q: What is the difference between it and Hastelloy C-276?

 

 

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