S32950

S32950

S32950 is a second-generation standard duplex stainless steel belonging to the austenitic-ferritic duplex stainless steel family, with a typical composition of 26-29% Cr, 3.5-5.2% Ni, 1.0-2.5% Mo, 0.15-0.35% N, and Fe as the balance. This alloy is characterized by a duplex microstructure consisting of approximately 50% ferrite and 50% austenite, combining the high strength and stress corrosion cracking resistance of ferritic stainless steels with the excellent ductility and weldability of austenitic stainless steels. S32950 exhibits outstanding resistance to pitting corrosion, crevice corrosion, and stress corrosion cracking in chloride environments, with a pitting resistance equivalent (PREN) of approximately 34-37, significantly outperforming 316L (PREN ≈ 25) and 317L. Compared to conventional austenitic stainless steels, S32950 has approximately twice the yield strength (≥ 485 MPa vs. 316L ≈ 220 MPa), along with higher thermal conductivity and lower thermal expansion coefficient. The alloy is widely used in harsh service conditions where both corrosion resistance and strength are required, such as in the oil and gas industry, chemical processing, offshore platforms, seawater desalination, heat exchangers, and high-pressure piping. Its elevated chromium, molybdenum, and nitrogen content enable it to resist chloride-induced pitting, crevice corrosion, and general corrosion, making it a cost-effective material for replacing austenitic stainless steels in chloride-containing environments. The product complies with international standards such as ASTM A240, ASTM A789, ASTM A182, and UNS S32950.
Send Inquiry
Description
Technical Parameters

Products Features

High-Temperature Oxidation Resistance

Excellent resistance to chloride stress corrosion cracking (core advantage)

One of the core advantages of S32950 is its excellent resistance to chloride stress corrosion cracking (SCC) brought about by its duplex microstructure. Austenitic stainless steels (such as 304L and 316L) are highly susceptible to SCC failure in chloride-containing environments under the combined influence of temperature, stress, and chloride ions. In contrast, the duplex structure of S32950 provides it with an inherent immunity to chloride-induced SCC. This characteristic makes it an ideal material choice for applications where chloride ions and stress coexist, such as offshore platforms, oil and gas processing equipment, and chemical plants.

High-Temperature Corrosion Resistance

High strength matched with good ductility

The yield strength of S32950 (≥ 485 MPa) is approximately twice that of 316L, with a tensile strength ≥ 690 MPa and an elongation ≥ 15%, along with good reduction of area. Its strength level is comparable to or even exceeds that of some low-alloy steels, while its ductility is far superior to that of ferritic stainless steels. At equivalent design strength, S32950 can achieve thinner wall thicknesses and lighter structural designs, thereby reducing material costs and manufacturing expenses.

High Stability

Excellent pitting and crevice corrosion resistance

The high chromium (26-29%), high molybdenum (1.0-2.5%), and high nitrogen (0.15-0.35%) content of S32950 endows it with exceptional resistance to pitting corrosion and crevice corrosion. Its PREN value is approximately 34-37, significantly higher than that of 316L (≈25). In harsh environments such as seawater, chloride solutions, and acidic chloride media, S32950 can form a stable passive film, resisting the initiation and propagation of pitting. Its critical pitting temperature (CPT) and critical crevice corrosion temperature (CCT) are notably higher than those of 316L and 317L.

Good Processability

Good welding performance

S32950 exhibits good weldability. Compared to the first-generation duplex stainless steels, second-generation duplex steels have significantly reduced sensitivity to welding thermal cycles. Various welding methods such as TIG, MIG, SMAW, and SAW can be used for joining. During welding, heat input and interpass temperature (typically ≤ 150°C) should be controlled to prevent the precipitation of harmful intermetallic phases (e.g., sigma phase). Post-weld solution annealing is generally not required, but pickling or passivation is recommended to restore corrosion resistance. The welded joints of S32950 maintain good resistance to stress corrosion cracking (SCC) in hot chloride environments, but additional corrosion assessment at the weld location is advised.

High-Temperature Oxidation Resistance

Good hot working and cold working properties

S32950 exhibits excellent hot working properties and can be formed through hot forging, hot rolling, hot extrusion, and other hot working processes within a temperature range of 950-1150°C. After hot working, solution treatment (approximately 1010-1150°C) is required to achieve the optimal duplex microstructure and mechanical properties. The alloy's cold working performance is superior to that of ferritic stainless steels, allowing for cold bending, cold rolling, stamping, and other forming operations. However, its tendency to work harden is higher than that of austenitic stainless steels.

Technical Specifications

Chemical Composition(ASTM A240 / UNS S32950)

 

Element

Standard Requirements

Notes

Cr

26.0 - 29.0%

Core elements that form a dense passivation film to provide corrosion resistance; ferrite-forming elements

Ni

3.5 - 5.2%

Austenite stabilizing elements promote the formation of duplex microstructure and enhance toughness

Mo

1.0 - 2.5%

Improves resistance to pitting and crevice corrosion, with an effect approximately three times that of chromium

N

0.15 - 0.35%

Strong austenite-forming elements, solid solution strengthening, improve pitting corrosion resistance

Mn

≤ 2.0%

Deoxidizer, added in small amounts

Si

≤ 0.60%

Deoxidizer, strictly controlled

C

≤ 0.030%

Strictly control to prevent the precipitation of carbides from impairing corrosion resistance

P

≤ 0.035%

Deoxidizer, strictly controlled

S

≤ 0.010%

Impurity elements, strictly controlled to prevent hot brittleness

Fe

Remaining quantity

(≈ 63.5%)

Matrix element

Physical Properties

 

Property

Value/Range

Test Conditions

Density

7.80 g/cm³

Room Temperature (20°C)

Melting Point

≈ 1450°C

-

Thermal Conductivity

≈ 17 W/(m·K)(100°C)

Superior to austenitic stainless steel

Coefficient of thermal expansion

(20-100°C)

≈ 11 × 10⁻⁶ /K

Superior to austenitic stainless steel

Resistivity

≈ 0.80 μΩ·m

Room Temperature

Elastic modulus (Young's modulus)

192 - 200 GPa

Room Temperature

Poisson's ratio

0.25 - 0.29

Room Temperature

Magnetism

Ferromagnetism

The duplex structure is magnetic

Mechanical Properties (Solution Annealed Condition, Typical Values, ASTM A240)

 

Property

Typical Value

Specification

Tensile Strength

≥ 690 MPa

ASTM A240

Yield Strength (0.2% Offset)

≥ 485 MPa

ASTM A240

Elongation

≥ 15%

ASTM A240

Hardness

≈ 31 HRC

-

Note: The yield strength of S32950 is approximately twice that of 316L, which can significantly reduce wall thickness, achieving structural lightweighting and cost optimization.

Pitting Resistance Equivalent Number (PREN) Comparison

 

Material grade

PREN(Cr+3.3Mo+16N)

Chloride resistance

S32950

≈ 34 - 37

Excellent

316L

≈ 25

General

317L

≈ 28

Good

2205 (S31803)

≈ 33 - 35

Excellent

Corrosion Resistance (Typical Value)

 

Medium

Concentration

Temperature

Corrosion rate

Rating

Seawater

-

Room temperature to high temperature

Ignored

Excellent

Chloride solution (salt water)

-

High Temperature

Ignored

Excellent

Nitric acid (HNO₃)

≤ 40%

Room Temperature

<0.05

Excellent

Sulfuric acid (H₂SO₄)

≤ 40%

Room Temperature

<0.1

Good

Hydrochloric acid (HCl)

Low concentration

Room Temperature

<0.1

Good

Sodium hydroxide (NaOH)

-

Room Temperature

Ignored

Excellent

Organic acids (such as acetic acid, citric acid, etc.)

-

Room Temperature

Ignored

Excellent

Wet Chlorine Gas

-

Room Temperature

Ignored

Excellent

Note: The corrosion resistance of S32950 is superior to that of 316L and 317L in most environments. It exhibits excellent resistance to stress corrosion cracking (SCC) in chloride-containing environments, but its corrosion resistance is limited in strongly reducing media such as high-temperature, high-concentration hydrochloric acid and hydrofluoric acid. In hydrogen-containing environments, duplex stainless steels are susceptible to hydrogen embrittlement and require careful evaluation.

High-temperature performance

 
 

High-temperature strength retention:

S32950 maintains high strength at moderate temperatures:

Temperature

Tensile Strength (MPa)

Performance retention rate

Room temperature (20°C)

≥ 690

100%

200°C

≈ 620

≥ 90%

300°C

≈ 560

≥ 81%

400°C

≈ 500

≥ 72%

Long-term thermal stability and organizational stability:

S32950 exhibits good microstructural stability during long-term service at temperatures ≤ 300°C

Note that prolonged exposure at temperatures between 300-500°C may lead to 475°C embrittlement (spinodal decomposition of the ferrite phase), resulting in reduced toughness. Therefore, long-term use within this temperature range is not recommended.

Prolonged exposure in the 600-900°C range may lead to the precipitation of the sigma phase (an intermetallic compound), significantly reducing corrosion resistance and toughness.

S32950 is less sensitive to harmful phase precipitation than first-generation duplex stainless steels, but strict control of cooling rate is still required during heat treatment and welding to quickly pass through the sensitive temperature range.

Antioxidant performance:

S32950 can form a protective oxide film below 800°C, and its oxidation resistance is better than that of austenitic stainless steel.

For long-term service at higher temperatures, it is recommended to evaluate oxidation weight gain.

Heat treatment system

The heat treatment of S32950 has a decisive impact on the final microstructure and properties, with common specifications as follows:

1. Solution treatment (for obtaining the optimal duplex microstructure and comprehensive properties):

Heat to 1010-1150°C, hold for a sufficient time (approximately 2-4 minutes per inch of thickness), then water quench or rapid air cool. This will yield an ideal duplex microstructure consisting of approximately 50% ferrite and 50% austenite, providing optimal corrosion resistance.

2. Stress Relief Treatment (After Welding/Cold Working):

Heat to 650-750°C, hold for 1-2 hours, then air cool. Used for relieving residual stresses,

However, note that sigma phase precipitation may occur in this temperature range; it is recommended to carefully evaluate its impact on corrosion resistance.

Note:

1. Heat treatment should quickly pass through the sensitive temperature range of 600-900°C to avoid precipitation of σ phase and χ phase.

2. The solution treatment temperature should not be too high (> 1150°C), otherwise excessive ferrite content will affect toughness and corrosion resistance.

3. It is recommended to perform pickling or passivation after heat treatment to remove surface scale.

Welding Performance and Process Key Points

S32950 has good welding properties, which is an important feature of the second-generation duplex stainless steel:

1. Recommended welding methods:

TIG (GTAW), MIG (GMAW), SMAW, SAW, FCAW.

2. Heat input control:

It is recommended that the heat input be 0.5-2.5 kJ/mm, and the interpass temperature be ≤ 150°C to avoid grain coarsening in the heat-affected zone and precipitation of harmful phases.

3. Protective gas:

It is recommended to use a mixed gas of Ar + 1-2% N₂, which can increase the austenite content in the weld metal, thereby improving the toughness and corrosion resistance of the weld.

4. Filler metal:

It is recommended to use duplex stainless steel filler metals such as 2209 or 2594 that are matched or over-matched to the base metal to ensure that the corrosion resistance of the weld is not lower than that of the base metal.

5. Post-weld treatment:

It is recommended to perform pickling or passivation to restore the corrosion resistance of the heat-affected zone and remove welding oxidation discoloration. Pickling is more effective than mechanical cleaning in removing chromium-depleted layers.

Comparison of Magnetic Properties and Application Selection

Performance indicators

S32950 (Duplex stainless steel)

316L (Duplex stainless steel)

2205 (Duplex stainless steel)

Yield strength

(MPa)

≥ 485

≈ 220

≥ 450

Tensile Strength (MPa)

≥ 690

≈ 520

≥ 620

Elongation

(%)

≥ 15

≥ 40

≥ 25

PREN (Pitting Corrosion Equivalent)

34 - 37

≈ 25

33 - 35

Resistance to SCC (Chlorides)

Excellent

Difference (Highly Sensitive)

Excellent

Magnetism

Ferromagnetism

Non-magnetic

Ferromagnetism

Thermal Conductivity

Higher

(≈17 W/m·K)

Lower

(≈14 W/m·K)

Higher

Price

Medium

Lower

Medium

Selection suggestions

Primarily used in high-strength, chlorine-resistant, and moderately corrosive environments: oil and gas, offshore platforms, seawater desalination, heat exchangers, high-pressure pipelines

Primarily used in general corrosion-resistant environments with requirements for chlorine-free, low-temperature, low-strength, and non-magnetic properties

It is primarily used for applications with higher strength and corrosion resistance requirements. Its PREN is similar to that of S32950, but it has a higher nickel content.

Applicable Media

1. Seawater and chloride solutions: Excellent resistance to pitting corrosion, crevice corrosion, and stress corrosion cracking.

2. Oxidizing acids: Such as nitric acid (≤40%), with excellent corrosion resistance.

3. Moderately concentrated reducing acids: Such as sulfuric acid (≤40%).

4. Organic acids: Acetic acid, citric acid, formic acid, etc.

5. Alkaline solutions: Sodium hydroxide, potassium hydroxide, etc.

6. Chlorine-containing oil and gas media: Petroleum and natural gas exploration and processing environments.

7. High-temperature water vapor (temperature limitations should be noted).

Note:

S32950 is not resistant to strongly reducing media such as hydrofluoric acid and high-temperature concentrated hydrochloric acid. In hydrogen-containing environments, duplex stainless steels are susceptible to hydrogen embrittlement and require careful evaluation. Long-term use conditions should avoid 475°C embrittlement and sigma phase precipitation.

Steel Plate Processing
Steel Coil Processing
Steel Pipe Processing
Steel Bar Processing
 

S32950 (UNS S32950) is suitable for applications with comprehensive requirements for high strength, chlorine resistance, and moderate corrosion. It is recommended for use in the following fields:

 

Application Fields

  •  

    Oil and Natural Gas Industry (Core Applications)
    ● Oil and gas field pipeline systems, gathering and transportation pipelines, submarine pipelines
    ● Downhole tools, wellhead equipment, valves, pipe fittings, flanges
    ● Separator, heat exchanger, pump and valve components
    ● Drilling platform modules, fire protection systems

  •  

    Chemical Processing and Petrochemical Engineering
    ● Pressure vessels, high-pressure tanks, reactors
    ● Heat exchangers, condensers, evaporators
    ● Pipeline system for conveying corrosive media (including chloride environments)
    ● Distillation column, absorption tower, separator

  •  

    Ocean Engineering and Seawater Desalination
    ● Desalination plant pipelines, high-pressure reverse osmosis (RO) units
    ● Offshore platform structural components, seawater heat exchangers
    ● Ship ballast water system, fire water system

  •  

    Pulp and Paper Industry
    ● Steaming vessels, bleaching equipment, washers, and storage processing systems

  •  

    Electric power industry
    ● FGD flue gas desulfurization system, absorber tower, pipelines and flue gas ducts
    ● Nuclear power secondary cooling water circuit pipeline

  •  

    Environmental Protection and Wastewater Treatment
    ● Wastewater treatment system, exhaust gas scrubber tower, wastewater treatment equipment

  •  

    Machinery and Structural Components
    ● High-pressure rotating shafts, pressing rolls, blades, impellers, fasteners, and mechanical and structural components for high-strength and corrosion-resistant environments

Delivery and Customization

We offer flexible and reliable supply chain solutions to ensure you receive S32950 materials that perfectly match your project requirements.

Form

image011
Sheet/Plate
image013
Bar/Rod
image015
Pipe / Tube
image017
Strip/Sheet Coil
image019
Wire/Wire Rod

Conventional Range

Thickness: 0.5 - 100 mm
Width: ≤ 1500 mm

Diameter Φ6-500mm

Outer diameter Φ10-300mm

Thickness: 0.1 – 3.0 mm
Width: 10 – 600 mm

Diameter Φ0.5-10mm

Customization Capability

Hot-rolled or cold-rolled plates, ultra-thin plates (starting from 0.1mm), stamped parts, length-cutting to specified dimensions, special surface treatments (pickling, polishing)

Forged bars, hot-rolled bars, polished bars, shaped bars, and different heat treatment conditions (solution-treated condition)

Seamless Tubes / Welded Tubes (Compliant with ASTM A789), Fixed Length Cutting, U-Tubes

Precision strip materials, stamping coil stock, laminated blanking, non-standard width, special protective film

Precision drawing, welding filler wire, special surface treatment

Why Choose Us? - Reliable Engineering Technology. Dependable Delivery.

We are not just a supplier, but a trusted materials partner for you in China.

Sample Support & Quick Response

Vertically Integrated Production

Own 20,000㎡ facility with 10+ automated lines (8,000+ tons/year). In-house tooling & die center enables rapid customization and effective cost control - no middleman markup.

Full Traceability

Strict Quality Control at Every Stage

Full traceability across key QC checkpoints throughout production. 100% compliant with ASTM/ASME, EN, and GB standards. Material test reports available with every shipment.

Professional Logistics & Packaging

Reliable Delivery & Export Packaging

10+ years exporting to Europe, North America, Southeast Asia & Middle East with waterproof and anti-rust protection, combined with flexible shipping options ensures safe and on-time arrival.

Complete Export Documentation

Sample Validation Before Mass Production

We provide free samples for quality verification, allowing you to place bulk orders only after approval. We ensure consistency from sample to mass production by accurate dimensional measurement and transparent manufacturing.

FAQ

Q: What are the main advantages of S32950?

 

Q: What is the difference between S32950 and 316L? How to choose between them?

 

Q: What is the difference between S32950 and 2205? How to choose between them?

 

Q: What is the maximum usage temperature for S32950?

 

Q: What is the welding performance of S32950?

 

Q: Can S32950 replace 316L?

 

 

Hot Tags: s32950, China s32950 manufacturers, suppliers, factory