S32750

S32750

S32750 (2507 Super Duplex Stainless Steel) is a third-generation super duplex stainless steel belonging to the austenitic-ferritic duplex stainless steel family. Its typical nominal composition includes 25% Cr, 7% Ni, 4% Mo, 0.27% N, with iron as the balance. It is one of the highest grades in terms of corrosion resistance and strength within the duplex stainless steel series. Characterized by a dual-phase microstructure consisting of approximately 50% ferrite and 50% austenite, this alloy combines the high strength and stress corrosion cracking resistance of ferritic stainless steels with the excellent ductility and weldability of austenitic stainless steels.
S32750 exhibits exceptional resistance to pitting corrosion, crevice corrosion, and stress corrosion cracking in chloride environments. Its Pitting Resistance Equivalent Number (PREN) is ≥ 40, significantly outperforming 316L (PREN ≈ 25) and 2205 (PREN ≈ 34-36). Compared to conventional austenitic stainless steels, S32750 offers approximately 2.5 times higher yield strength (≥ 550 MPa vs. 316L ≈ 220 MPa), along with a relatively high thermal conductivity and low coefficient of thermal expansion. This alloy is widely used in harsh service conditions where extremely high combined requirements for corrosion resistance and strength are imposed, such as in the oil and gas industry, chemical processing, offshore platforms, seawater desalination, heat exchangers, and high-pressure piping. It stands as the most corrosion-resistant and strongest grade among duplex stainless steels. Leveraging its exceptionally high PREN value (≥ 40), S32750 performs outstandingly in extreme corrosive environments featuring high chlorides, elevated temperatures, and strong acids, serving as a cost-effective alternative to austenitic stainless steels and certain nickel-based alloys. The product complies with international standards including ASTM A240, ASTM A789, ASTM A182, and UNS S32750.
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Description
Technical Parameters

Products Features

High-Temperature Oxidation Resistance

Exceptional resistance to pitting and crevice corrosion (core advantage)

One of the core advantages of S32750 is its extremely high resistance to pitting corrosion and crevice corrosion. The synergistic effect of high chromium (24-26%), high molybdenum (3.0-5.0%), and high nitrogen (0.24-0.32%) results in a PREN value ≥ 40, significantly higher than that of 316L (≈ 25) and 2205 (≈ 34-36). In harsh environments such as seawater, chloride solutions, and acidic chloride media, S32750 can form an exceptionally stable passive film, resisting the initiation and propagation of pitting and crevice corrosion. Its critical pitting temperature (CPT) reaches 45-50°C, far exceeding those of 316L and 2205, allowing it to operate reliably for long periods without pitting perforation in tropical seawater and high-temperature concentrated chloride solutions. This characteristic makes it an ideal material selection for extreme corrosion environments such as offshore platforms, seawater desalination, and oil and gas production.

High-Temperature Corrosion Resistance

Excellent resistance to chloride stress corrosion cracking

The duplex structure of S32750 provides it with inherent immunity to chloride-induced stress corrosion cracking (SCC). Conventional austenitic stainless steels are highly susceptible to intergranular SCC in chloride-containing aqueous solutions above 60°C, whereas S32750 exhibits significantly superior SCC resistance to austenitic stainless steels even in high-temperature chloride water above 100°C. This property makes it an ideal material selection for applications where chlorides, high temperatures, and stress coexist, such as offshore platforms, oil and gas processing equipment, and chemical plants. The alloy also complies with the NACE MR0175/ISO 15156 standard, making it suitable for acidic oil and gas environments containing hydrogen sulfide.

High Stability

High strength matched with good ductility

The yield strength of S32750 (≥ 550 MPa) is approximately 2.5 times that of 316L, with a tensile strength of ≥ 800 MPa and an elongation of ≥ 15%. Its strength level is comparable to or even exceeds that of some low-alloy steels, while its ductility is far superior to that of ferritic stainless steels. At equivalent design strength, S32750 can achieve significant wall thickness reduction and structural lightweighting, thereby substantially lowering material and manufacturing costs.

Good Processability

Good welding performance

S32750 exhibits good welding properties. Compared to the first-generation duplex stainless steels, third-generation super duplex steels have increased sensitivity to welding thermal cycles but can still achieve high-quality welding through strict process control. Various welding methods such as TIG, MIG, SMAW, and SAW can be used for joining. During welding, strict control of heat input (recommended 0.5-2.5 kJ/mm) and interpass temperature (typically ≤ 100-150°C) is required to prevent the precipitation of harmful intermetallic phases (such as sigma phase). Post-weld heat treatment is generally not required, but pickling or passivation is recommended to restore corrosion resistance. Matching filler materials such as ER2594 are recommended to ensure the weld forms approximately 30-50% ferrite microstructure.

High-Temperature Oxidation Resistance

Good hot working and cold working properties

S32750 exhibits excellent hot working properties and can be formed through hot forging, hot rolling, hot extrusion, and other hot working processes within a temperature range of 950-1250°C. The optimal hot working temperature interval is 1000-1150°C. After hot working, solution treatment (approximately 1050-1125°C) is required to achieve the best duplex microstructure and mechanical properties. The cold working performance of this alloy is superior to that of ferritic stainless steels, allowing for cold bending, cold rolling, stamping, and other forming operations. However, its tendency to work harden is higher than that of austenitic stainless steels. It is recommended to perform intermediate annealing when the cold deformation exceeds 5-10%.

Technical Specifications

Chemical Composition(ASTM A240 / UNS S32750)

 

Element

Standard Requirements

Notes

Cr

24.0 - 26.0%

Core elements that form a dense passivation film to provide corrosion resistance; ferrite-forming elements

Ni

6.0 - 8.0%

Austenite stabilizing elements promote the formation of a duplex microstructure and enhance toughness.

Mo

3.0 - 5.0%

Improves resistance to pitting and crevice corrosion by approximately three times that of chromium

N

0.24 - 0.32%

Strong austenite-forming elements, solid solution strengthening, significantly improve pitting corrosion resistance and yield strength

Mn

≤ 1.2%

Deoxidizer, added in small amounts

Si

≤ 0.80%

Deoxidizer, strictly controlled

C

≤ 0.030%

Strictly control to prevent the precipitation of carbides from impairing corrosion resistance

P

≤ 0.035%

Impurity elements, strictly controlled

S

≤ 0.020%

Impurity elements, strictly controlled to prevent hot brittleness

Fe

Remaining quantity (≈ 60%)

Matrix element

Physical Properties

 

Property

Value/Range

Test Conditions

Density

7.80 g/cm³

Room Temperature (20°C)

Melting Point

1300 - 1400°C

-

Thermal Conductivity

≈ 16 W/(m·K)

Room Temperature

Coefficient of thermal expansion

(20-100°C)

≈ 12.0 × 10⁻⁶ /K

Below austenitic stainless steel

Resistivity

≈ 0.85 μΩ·m

Room Temperature

Elastic modulus (Young's modulus)

190 - 200 GPa

Room Temperature

Poisson's ratio

0.25 - 0.29

Room Temperature

Magnetism

Ferromagnetism

The duplex structure is magnetic

Mechanical Properties (Solution Annealed Condition, Typical Value, ASTM A240)

 

Property

Typical Value

Specification

Tensile Strength

≥ 800 MPa

ASTM A240

Yield Strength (0.2% Offset)

≥ 550 MPa

ASTM A240

longation

≥ 15%

ASTM A240

Hardness (Burgundy)

310 HB(Maximum)

-

Note: The yield strength of S32750 is approximately 2.5 times that of 316L, allowing for a significant reduction in wall thickness to achieve structural lightweighting and cost optimization. With a PREN value of ≥40, it is the grade with the highest corrosion resistance among duplex stainless steels.

Pitting Resistance Equivalent Number (PREN) Comparison

 

Material grade

PREN(Cr+3.3Mo+16N)

Chloride resistance

S32750 (2507)

≥ 40

Extremely good

S32205 (2205)

34 - 36

Excellent

S31803 (2205)

32 - 39

Excellent

316L

≈ 25

General

Corrosion Resistance (Typical Value)

 

Medium

Concentration

Temperature

Corrosion rate

Rating

Seawater

-

Room temperature to high temperature

Ignored

Extremely good

Chloride solution (salt water)

-

High temperature

Ignored

Extremely good

Nitric acid (HNO₃)

≤ 40%

Room Temperature

<0.05

Excellent

Sulfuric acid (H₂SO₄)

≤ 40%

Room Temperature

<0.1

Excellent

Hydrochloric acid (HCl)

Low concentration

Room Temperature

<0.1

Good

Sodium hydroxide (NaOH)

-

Room Temperature

Ignored

Excellent

Organic acids (such as acetic acid, citric acid, etc.)

-

Room Temperature

Ignored

Excellent

Wet Chlorine Gas

-

Room Temperature

Ignored

Excellent

Note: The corrosion resistance of S32750 is significantly superior to that of 316L and 2205 in most environments. It exhibits excellent resistance to stress corrosion cracking (SCC) in chloride-containing environments, but its corrosion resistance is limited in strongly reducing media such as high-temperature concentrated hydrochloric acid, hydrofluoric acid, and concentrated sulfuric acid. In hydrogen-containing environments, duplex stainless steels are susceptible to hydrogen embrittlement and require careful evaluation.

High-temperature performance

 
 

High-temperature strength retention:

S32750 maintains high strength at moderate temperatures:

Temperature

Tensile strength (MPa)

Performance retention rate

Room Temperature (20°C)

≥ 800

100%

200°C

≈ 720

≥ 90%

300°C

≈ 650

≥ 81%

Long-term thermal stability and microstructural stability:

S32750 exhibits good microstructural stability when in service at temperatures ≤ 300°C for extended periods.

Note:

Prolonged exposure to temperatures between 300-500°C may lead to 475°C embrittlement (spinodal decomposition of the ferrite phase), resulting in reduced toughness. Therefore, long-term use within this temperature range is not recommended.

Prolonged exposure in the 600-900°C range may lead to the precipitation of the sigma phase (an intermetallic compound), which significantly reduces corrosion resistance and toughness. Solution treatment must quickly pass through this temperature range.

S32750 is more sensitive to harmful phase precipitation than 2205, requiring strict control of cooling rates during heat treatment and welding to quickly pass through the sensitive temperature range.

Antioxidant Performance:

S32750 can form a protective oxide layer below ≤ 800°C, offering better antioxidant properties than austenitic stainless steels. For long-term service at higher temperatures, it is recommended to evaluate oxidation weight gain.

Heat treatment system

The heat treatment of S32750 has a decisive impact on the final microstructure and properties, with common specifications as follows:

1. Solution Treatment (for obtaining the optimal duplex microstructure and comprehensive properties):

Heat to 1050-1125°C, hold for sufficient time (approximately 2-4 minutes per inch of thickness), then water quench or rapid air cool. This results in an ideal duplex microstructure of approximately 50% ferrite + 50% austenite and optimal corrosion resistance.

Stress Relief Heat Treatment (After Welding/Cold Working):

Heat to 650-750°C, hold for 1-2 hours, then air cool. Used to eliminate residual stresses. However, note that sigma phase precipitation may occur in this temperature range; it is recommended to carefully assess the impact on corrosion resistance.

Note:

Heat treatment should quickly pass through the sensitive temperature range of 600-900°C to avoid the precipitation of σ phase and χ phase.

The solution treatment temperature should not be too high (> 1125°C), otherwise the ferrite content will be excessive, affecting toughness and corrosion resistance.

It is recommended to perform pickling or passivation after heat treatment to remove surface scale

Welding Performance and Process Key Points

S32750 has good welding properties, but stricter control of process parameters is required:

Recommended welding methods:

TIG (GTAW), MIG (GMAW), SMAW, SAW, FCAW.

2. Heat input control:

It is recommended to maintain a heat input of 0.5-2.5 kJ/mm and interpass temperature ≤ 100-150°C to prevent grain coarsening and precipitation of harmful phases in the heat-affected zone. Compared to 2205, S32750 is more sensitive to heat input and requires strict control.

3. Protective gas:

It is recommended to use a mixed gas of Ar + 1-2% N₂, which can increase the austenite content in the weld metal, thereby improving the toughness and corrosion resistance of the weld.

4. Filler metal:

It is recommended to use super duplex stainless steel filler metals such as ER2594 or E2594 that are matched or over-matched to the base metal, to ensure that the corrosion resistance of the weld is not lower than that of the base metal.

5. Post-weld treatment:

It is recommended to perform pickling or passivation to restore the corrosion resistance of the heat-affected zone and remove welding oxidation discoloration. Pickling is more effective than mechanical cleaning in removing chromium-depleted layers.

Comparison of Magnetic Properties and Application Selection

Performance indicators

S32750

(2507 Super Duplex Stainless Steel)

316L

(Austenitic stainless steel)

S32205

(2205 Duplex Stainless Steel)

Yield Strength (MPa)

≥ 550

≈ 220

≥ 450

Tensile Strength (MPa)

≥ 800

≈ 520

≥ 620

Elongation (%)

≥ 15

≥ 40

≥ 25

PREN (Pitting Resistance Equivalent Number)

≥ 40

≈ 25

34 - 36

Resistance to SCC (Chlorides)

Extremely good

Difference (Highly Sensitive)

Excellent

Critical Pitting Temperature (CPT)

45-50°C

≈ 10°C

≈ 25-35°C

Magnetism

Ferromagnetism

Non-magnetic

Ferromagnetism

Thermal Conductivity

Higher (≈16 W/m·K)

Lower(≈14 W/m·K)

Higher (≈15 W/m·K)

Price

Higher

Lower

Medium

Selection suggestions

Primarily used in extreme corrosive environments such as high chlorides, high temperatures, and strong acids: offshore platforms, seawater desalination, oil and gas, and chemical equipment

Primarily used in general corrosion-resistant environments with requirements for chlorine-free, low-temperature, low-strength, and non-magnetic properties

General-purpose duplex stainless steel with the best cost-performance ratio, primarily used in moderately corrosive environments

Applicable Media

Seawater and chloride solutions:

Excellent resistance to pitting corrosion, crevice corrosion, and stress corrosion cracking.

Oxidizing acids:

Such as nitric acid (≤40%), with superior corrosion resistance.

Moderately concentrated reducing acids:

Such as sulfuric acid (≤40%).

Organic acids:

Acetic acid, citric acid, formic acid, etc.

5. Alkaline solutions:

Sodium hydroxide, potassium hydroxide, etc.

6. Chloride-containing oil and gas media:

Environments for oil and natural gas exploration and processing, compliant with NACE MR0175 standard.

7. High-temperature water vapor (temperature limitations should be noted).

Note:

S32750 is not resistant to strongly reducing media such as hydrofluoric acid and high-temperature, high-concentration hydrochloric acid.

In hydrogen-containing environments, duplex stainless steels are susceptible to hydrogen embrittlement and require careful evaluation.

Long-term use conditions to be avoided include 475°C embrittlement and σ-phase precipitation.

Steel Plate Processing
Steel Coil Processing
Steel Pipe Processing
Steel Bar Processing
 

S32750 (2507 Super Duplex Stainless Steel) is suitable for harsh service conditions with comprehensive requirements for extremely high strength, chlorine resistance, and corrosion resistance. It is recommended for use in the following fields:

 

Application Fields

  •  

    Oil and Natural Gas Industry (Core Applications)
    ● Oil and gas field pipeline systems, gathering and transportation pipelines, subsea pipelines, risers
    ● Downhole tools, wellhead equipment, valves, pipe fittings, flanges
    ● Separator, heat exchanger, pump and valve components
    ● Drilling platform modules, fire protection systems, seawater lift pumps
    ● Equipment for acidic oil and gas environments compliant with NACE MR0175 standard

  •  

    Chemical Processing and Petrochemical Engineering
    ● Pressure vessels, high-pressure tanks, reactors
    ● Heat exchangers, condensers, evaporators
    ● Pipeline system for conveying corrosive media (including chloride environments)
    ● Distillation column, absorption tower, separator
    ● Chlorate Manufacturing Equipment

  •  

    Ocean Engineering and Seawater Desalination
    ● Desalination plant pipelines, high-pressure reverse osmosis (RO) units
    ● Offshore platform structural components, seawater heat exchangers
    ● Ship ballast water system, fire water system

  •  

    Pulp and Paper Industry
    ● Steaming vessels, bleaching equipment, washers, and storage processing systems

  •  

    Electric Power Industry
    ● FGD flue gas desulfurization system, absorber tower, pipelines and flue gas ducts
    ● Nuclear power secondary cooling water circuit pipeline
    ● Geothermal power generation equipment

  •  

    Environmental Protection and Wastewater Treatment
    ● Wastewater treatment system, exhaust gas scrubber tower, wastewater treatment equipment
    ● Waste incineration flue gas treatment equipment

  •  

    Mechanical and Structural Components
    ● High-pressure rotating shafts, pressing rolls, blades, impellers, fasteners, and mechanical and structural components for high-strength and corrosion-resistant environments
    ● Pressure vessels, food processing equipment

Delivery and Customization

We offer flexible and reliable supply chain solutions to ensure you receive S32750 (2507 Super Duplex Stainless Steel) materials that perfectly match your project requirements.

Form

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Sheet/Plate
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Bar/Rod
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Pipe / Tube
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Strip/Sheet Coil
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Wire/Wire Rod

Conventional Range

Thickness: 0.5 - 100 mm
Width: ≤ 1500 mm

Diameter Φ6-500mm

Outer diameter Φ10-300mm

Thickness: 0.1 – 3.0 mm
Width: 10 - 600 mm

Diameter Φ0.5-10mm

Customization Capability

Hot-rolled or cold-rolled plates, ultra-thin plates (starting from 0.1mm), stamped parts, length-cutting to specified dimensions, special surface treatments (pickling, polishing)

Forged bars, hot-rolled bars, polished bars, shaped bars, and different heat treatment conditions (annealing, stabilization)

Seamless Tubes/ Welded Tubes (Compliant with ASTM A789/ A790), Fixed-Length Cutting, U-Tubes

Precision strip materials, stamping coil stock, laminated blanking, non-standard width, special protective film

Precision drawing, welding filler wire (ER2594), special surface treatment

Why Choose Us? - Reliable Engineering Technology. Dependable Delivery.

We are not just a supplier, but a trusted materials partner for you in China.

Sample Support & Quick Response

Vertically Integrated Production

Own 20,000㎡ facility with 10+ automated lines (8,000+ tons/year). In-house tooling & die center enables rapid customization and effective cost control - no middleman markup.

Full Traceability

Strict Quality Control at Every Stage

Full traceability across key QC checkpoints throughout production. 100% compliant with ASTM/ASME, EN, and GB standards. Material test reports available with every shipment.

Professional Logistics & Packaging

Reliable Delivery & Export Packaging

10+ years exporting to Europe, North America, Southeast Asia & Middle East with waterproof and anti-rust protection, combined with flexible shipping options ensures safe and on-time arrival.

Complete Export Documentation

Sample Validation Before Mass Production

We provide free samples for quality verification, allowing you to place bulk orders only after approval. We ensure consistency from sample to mass production by accurate dimensional measurement and transparent manufacturing.

FAQ

Q: What are the main advantages of S32750 (2507 super duplex stainless steel)?

 

Q: What is the difference between S32750 and 316L? How to choose?

 

Q: What is the difference between S32750 and S32205 (2205)? How to choose?

 

Q: What is the maximum usage temperature for S32750?

 

Q: What is the welding performance of S32750?

 

 

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