ASTM A333

ASTM A333

ASTM A333 (ASME SA333) is a core American standard specification for seamless and welded carbon steel and alloy steel pipes intended for low-temperature service. It covers multiple grades from Grade 1 to Grade 11 and is one of the most widely used and broadly temperature-range-covered specifications for American low-temperature carbon steel pipes. This material is specifically designed for low- and ultra-low-temperature conditions and is a classic material choice for low-temperature pressure equipment applications such as LNG receiving terminals, air separation plants, low-temperature liquid transportation, and petrochemical cryogenic equipment.
The core characteristics of ASTM A333 lie in the balance between excellent low-temperature impact toughness and good overall performance. The specification requires materials to pass Charpy V-notch impact tests at specified low temperatures, ensuring sufficient resistance to brittle fracture under low-temperature service conditions. Grade 6 is the most widely used grade (minimum service temperature approximately -46°C), offering an outstanding balance of strength, weldability, low-temperature toughness, and cost, making it the industry-standard material for low-temperature process piping. Grade 3 is a low-temperature steel containing 3.5% nickel (minimum service temperature approximately -101°C), and Grade 8 is a low-temperature steel containing 9% nickel (minimum service temperature approximately -196°C). These grades can be flexibly selected based on specific operating condition requirements. The product complies with international standards such as ASTM A333 / ASME SA333.
Key Highlights: ASTM A333 Grade 6 is the preferred grade for American standard low-temperature carbon steel seamless pipes. It is the most widely used in low-temperature process piping of LNG receiving terminals and air separation plants, and serves as the industry standard for low-temperature carbon steel pipes.
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Description
Technical Parameters

Products Features

High-Temperature Oxidation Resistance

Excellent low-temperature impact toughness (core advantage)

The core advantage of ASTM A333 lies in its excellent low-temperature impact toughness. This specification mandates Charpy V-notch impact testing of the material at specified low temperatures, ensuring sufficient resistance to brittle fracture under low-temperature service conditions. Grade 6 has an average impact energy of ≥ 18J and a minimum single value of ≥ 13J at -46°C, effectively mitigating the risk of brittle fracture in materials at low temperatures and ensuring the safety and reliability of pipelines during low-temperature service.

High-Temperature Corrosion Resistance

Good welding performance

The low carbon equivalent design of ASTM A333 ensures good weldability with a mature welding process, making it suitable for large-scale on-site installation. When welding low-temperature steel, strict control of heat input is required to prevent a decrease in the toughness of the heat-affected zone. Preheating is generally not necessary before welding (except for thick-walled pipes or in low-temperature environments), and post-weld heat treatment at 600-650°C can be optionally performed after welding to relieve residual stresses.

High Stability

Good machinability

It can undergo various forming processes such as hot bending, cold bending, and forging, making it suitable for manufacturing pipe fittings like elbows, tees, and reducers. It can also be machined using conventional machining methods. It should be noted that Grades 3 (3.5% Ni) and 8 (9% Ni), due to their higher nickel content, have a slightly higher tendency for work hardening compared to Grade 6.

Good Processability

Mature technology and long-term reliability

It exhibits good organizational stability during long-term service within their respective applicable temperature ranges (Grade 6 ≤ -46°C / Grade 3 ≤ -101°C / Grade 8 ≤ -196°C). Delivered in normalized or normalized plus tempered condition, it achieves a uniform and fine microstructure, ensuring organizational stability and reliability under low-temperature service conditions.

Technical Specifications

Chemical Composition(ASTM A333 / ASME SA333)

 

Element

Grade 1

Grade 3

Grade 4

Grade 6

Grade 7

Grade 8

Grade 9

Note

C

≤ 0.30%

≤ 0.19%

≤ 0.12%

≤ 0.30%

≤ 0.19%

≤ 0.13%

≤ 0.20%

Ensure low-temperature toughness and weldability

Mn

0.40-1.06%

0.31-0.64%

0.50-1.05%

0.29-1.06%

≤ 0.90%

≤ 0.90%

0.40-1.06%

Solid solution strengthening, improve strength

P

≤ 0.035%

≤ 0.035%

≤ 0.035%

≤ 0.035%

≤ 0.035%

≤ 0.035%

≤ 0.035%

Harmful elements, strictly controlled

S

≤ 0.035%

≤ 0.035%

≤ 0.035%

≤ 0.035%

≤ 0.035%

≤ 0.035%

≤ 0.035%

Harmful elements, strictly controlled

Si

0.10-0.35%

0.13-0.32%

0.18-0.37%

≥ 0.10%

0.13-0.32%

0.13-0.32%

0.13-0.32%

Deoxidizer

Ni

-

3.18-3.82%

0.47-0.98%

-

2.03-2.57%

8.40-9.60%

1.60-2.24%

Elements of Low-Temperature Toughness

Cr

-

-

0.44-1.01%

-

-

-

-

Improve hardenability

Cu

-

-

0.40-0.70%

-

-

-

-

Improve corrosion resistance

Mo

-

-

0.40-0.75%

-

-

-

-

Enhance high-temperature strength

Fe

Remaining quantity

Remaining quantity

Remaining quantity

Remaining quantity

Remaining quantity

Remaining quantity

Remaining quantity

Matrix element

Physical Properties

 

Performance

Numerical Value/Range

Test conditions

Density

≈ 7.85 g/cm³

Room temperature (20°C)

Melting Point

≈ 1420-1460°C

-

Elastic modulus

≈ 200 GPa

Room temperature

Thermal Conductivity

≈ 50 W/(m·K)

Room temperature

Coefficient of thermal expansion (20-100°C)

≈ 11.7 × 10⁻⁶ /K

-

Poisson's ratio

≈ 0.28

Room temperature

Magnetism

Ferromagnetic

Carbon steel/ low-alloy steel, which is magnetic

Mechanical Properties (Typical value, ASTM A333)

 

Performance

Grade 1

Grade 3

Grade 4

Grade 6

Grade 7

Grade 8

Grade 9

Specification

Tensile Strength

≥ 380 MPa

≥ 450 MPa

≥ 415 MPa

≥ 415 MPa

≥ 450 MPa

≥ 690 MPa

≥ 435 MPa

ASTM A333

Yield strength

≥ 205 MPa

≥ 240 MPa

≥ 240 MPa

≥ 240 MPa

≥ 205 MPa

≥ 515 MPa

≥ 315 MPa

ASTM A333

Elongation

≥ 35%

≥ 30%

≥ 30%

≥ 30%

≥ 30%

≥ 22%

≥ 28%

ASTM A333

Impact test temperature

-46°C

-101°C

-46°C

-46°C

-73°C

-196°C

-73°C

ASTM A333

Impact Toughness (Average Value)

≥ 18J

≥ 18J

≥ 18J

≥ 18J

≥ 18J

≥ 18J

≥ 18J

ASTM A333

Note: Note: Grade 6 is the most widely used grade in the ASTM A333 standard, offering an excellent balance between strength, weldability, low-temperature toughness, and cost, suitable for low-temperature service conditions down to -46°C. Grade 3 (3.5% Ni) is applicable for -101°C, and Grade 8 (9% Ni) for -196°C.

Low-temperature Impact Performance (Core Indicator)

 

Grade

Minimum operating temperature

Impact test temperature

Minimum Impact Energy (Average Value)

Minimum impact energy (single value)

Typical applications

Grade 1

-46°C

-46°C

≥ 18J

≥ 13J

General low-temperature conditions

Grade 3

-101°C

-101°C

≥ 18J

≥ 13J

LNG, air separation unit

Grade 4

-46°C

-46°C

≥ 18J

≥ 13J

Low-temperature sulfur-containing environment

Grade 6

-46°C

-46°C

≥ 18J

≥ 13J

Most commonly used, preferred for -46°C low-temperature conditions

Grade 7

-73°C

-73°C

≥ 18J

≥ 13J

Lower temperature requirements

Grade 8

-196°C

-196°C

≥ 18J

≥ 13J

LNG storage tanks, liquid nitrogen/ liquid oxygen pipelines

Grade 9

-73°C

-73°C

≥ 18J

≥ 13J

Petrochemical deep cryogenic equipment

Heat treatment system

 
 

The final performance of ASTM A333 is highly dependent on the heat treatment regime:

Normalizing

Heat to 845-925°C, hold for sufficient time, then air cool. This results in a uniform and fine-grained microstructure, improving low-temperature toughness. The normalizing temperature for Grade 8 is typically 845-900°C, slightly higher than other grades.

Normalizing + Tempering (Recommended for Grade 8)

After normalizing, heat to 565-650°C for tempering, then air cool. This eliminates normalizing stresses and further optimizes low-temperature toughness.

Full Annealing (Optional)

Heat to 815-870°C, hold at temperature, then furnace cool to approximately 650°C, followed by air cooling to room temperature. Used to eliminate cold working stresses or improve cold working formability.

Post-Weld Heat Treatment (PWHT, selected based on wall thickness and operating conditions)

Heat to 600-650°C, hold at temperature, then cool slowly to eliminate residual welding stresses.

Applicable Media

Liquefied Natural Gas (LNG)

LNG receiving terminals, low-temperature pipelines of liquefaction plants (≤ -162°C)

Air separation unit

liquid oxygen, liquid nitrogen, liquid argon pipelines and cold box pipelines

Low-temperature liquids

Transportation of low-temperature media such as liquid ethylene, liquid ammonia, and liquid hydrogen

Petrochemical Deep Cryogenics

Deep Cryogenic Separation of Ethylene Plants, Low-Temperature Process Piping

Low-Temperature Storage Tanks

LNG storage tank pipelines, low-temperature spherical tanks

Note: Each grade of ASTM A333 has different applicable minimum temperature limits. Grade 6 is suitable for temperatures above -46°C, Grade 3 for above -101°C, and Grade 8 for above -196°C. When selecting materials, the appropriate grade should be chosen based on the minimum design temperature. It is not applicable to high-temperature conditions (above 350°C) and strongly corrosive media such as strongly oxidizing acids.

Steel Plate Processing
Steel Coil Processing
Steel Pipe Processing
Steel Bar Processing
 

ASTM A333 is suitable for low-temperature service ranging from -46°C to -196°C and is recommended for use in the following areas:

 

Application Fields

  •  

    LNG receiving terminals and liquefaction plants (core applications, Grade 3 / Grade 8)
    ● LNG unloading pipelines, vapor (BOG) pipelines
    ● LNG transportation pipelines (≤ -162°C)
    ● LNG Tank Accompanying Pipeline System

  •  

    Air Separation and Industrial Gases (Core Applications, Grade 6 / Grade 3)
    ● Liquid Oxygen, Liquid Nitrogen, and Liquid Argon Piping Systems (-183°C ~ -196°C)
    ● Cold Box Piping Systems for Air Separation Units
    ● Low-Temperature Piping for Industrial Gas Separation Equipment

  •  

    Petrochemical Deep Cryogenics (Core Applications, Grade 6 / Grade 7 / Grade 9)
    ● Deep Cryogenic Separation Pipelines for Ethylene Cracking Units (-100°C ~ -160°C)
    ● Low-temperature transportation pipelines for propylene and butadiene
    ● Low-temperature methanol wash (Rectisol) process piping

  •  

    Low-temperature storage and transportation
    ● Piping system for low-temperature liquid storage tanks
    ● Filling pipeline system for low-temperature tank trucks
    ● Pipelines for liquefied gas transport ships

  •  

    Low-temperature pipe fittings
    ● Low-temperature elbows, tees, reducers
    ● Low-temperature forged pipe fittings, flanges

Delivery and Customization

We offer flexible and reliable supply chain solutions to ensure you receive ASTM A333 low-temperature seamless steel pipes that perfectly match your project requirements.
Customizable material forms
We support producing various basic and special shapes according to drawings or specifications.

Form

1
Hot-rolled seamless steel pipe
2
Cold-drawn seamless steel pipe
3
Large-diameter thick-walled pipe

Conventional Range

Diameter: 60.3 - 1067 mm; Wall Thickness: 3 - 150 mm

Outer Diameter: 10.3 - 114.3 mm; Wall Thickness: 1 - 15 mm

Outer Diameter: 219 - 1067 mm; Wall Thickness: 20 - 150 mm

Customization Capability

Fixed-length cutting, bevel processing, pipe end threads, normalized/ annealed condition

Precision Dimension Control, Bright Annealing, Fixed-Length Cutting

Hot expansion of tubes, fixed-length cutting, bevel machining

Why Choose Us? - Reliable Engineering Technology. Dependable Delivery.

We are not just a supplier, but a trusted materials partner for you in China.

Sample Support & Quick Response

Vertically Integrated Production

Own 20,000㎡ facility with 10+ automated lines (8,000+ tons/year). In-house tooling & die center enables rapid customization and effective cost control - no middleman markup.

Full Traceability

Strict Quality Control at Every Stage

Full traceability across key QC checkpoints throughout production. 100% compliant with ASTM/ASME, EN, and GB standards. Material test reports available with every shipment.

Professional Logistics & Packaging

Reliable Delivery & Export Packaging

10+ years exporting to Europe, North America, Southeast Asia & Middle East with waterproof and anti-rust protection, combined with flexible shipping options ensures safe and on-time arrival.

Complete Export Documentation

Sample Validation Before Mass Production

We provide free samples for quality verification, allowing you to place bulk orders only after approval. We ensure consistency from sample to mass production by accurate dimensional measurement and transparent manufacturing.

FAQ

Q: What are the main advantages of ASTM A333 Grade 6?

 

Q: What is the difference between ASTM A333 Grade 6 and ASTM A106 Grade B? How to choose between them?

 

Q: How to select the commonly used grades of ASTM A333?

 

Q: What is the minimum service temperature for ASTM A333 Grade 6?

 

Q: What is the welding performance of ASTM A333 Grade 6?

 

Q: What is the corrosion resistance of ASTM A333 Grade 6?

 

 

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